We are entering an era that emphasizes greenness and sustainability. Based on such a
philosophy, it is critical to uncover novel and original sustainable reaction modes for future …

Transition metal-catalyzed direct functionalization of C–H bonds is one of the key emerging
strategies that is currently attracting tremendous attention with the aim to provide alternative …

The various applications of hydrogen isotopes (deuterium, D, and tritium, T) in the physical
and life sciences demand a range of methods for their installation in an array of molecular …

Conspectus The possibility of develo** new methods for the efficient construction of
organic molecules via disconnections other than traditional functional group transformations …

Rhodium (III)-catalyzed direct functionalization of C–H bonds under oxidative conditions
leading to C–C, C–N, and C–O bond formation is reviewed. Various arene substrates …

Inspired by the need for green and sustainable chemistry,(1) synthetic chemists seek more
efficient ways to construct carbon− carbon (C− C) bonds, the essential link in all organic …

The transition metal-catalyzed transformation of otherwise inert C–H bonds into substituted
alkenes offers a versatile tool for the synthesis of value added olefinic molecules. Recent …

The development of new strategies and chemical reactions continues to be a major focus of
research efforts in the modern synthetic organic community. 1 Of the various types of …

Directing groups that can act as internal oxidants have recently been shown to be beneficial
in metal-catalyzed heterocycle syntheses that undergo C− H functionalization. Pursuant to …

Significant progress has been accomplished in direct olefinations through twofold C–H bond
functionalization of arenes and heteroarenes employing readily accessible, selective and …