Direct photocatalyzed hydrogen atom transfer (d-HAT) can be considered a method of
choice for the elaboration of aliphatic C–H bonds. In this manifold, a photocatalyst (PCHAT) …

Redox processes are at the heart of synthetic methods that rely on either electrochemistry or
photoredox catalysis, but how do electrochemistry and photoredox catalysis compare? Both …

Functionalization of the benzylic C (sp 3)–H bond has become a compelling and robust tool
to speed up pre-clinical research for" lead discovery." Besides bring frequently utilizated to …

The electrochemical utilization of electron-deficient methylarenes for radical–radical cross-
couplings remains very rare. Enabled by an umpolung strategy, the unprecedented …

Without employing an external oxidant, the simple synthesis of 3-halochromones and
various halogenated electron-rich arenes has been realized with electrode oxidation by …

A metal-free electrophotochemical C (sp3)-H arylation was developed under mild
conditions. This method enables a switchable synthesis of diaryl alcohols and diaryl alkanes …

Activation of ubiquitous C (sp3)− H bonds is extremely attractive but remains a great
challenge. Heterogeneous photocatalysis offers a promising and sustainable approach for C …

Despite their prevalence in organic synthesis, the application of boronic acids (BAs) as alkyl
radical precursors in visible-light-assisted photocatalyzed reactions has been limited by their …

The site-selective modification of peptide backbones allows an outstanding fine-tuning of
peptide conformation, folding ability, and physico-chemical and biological properties …

The development of sustainable C (sp3)–H functionalization methods is of great interest to
the pharmaceutical and agrochemical industries. Anodic oxidation is an efficient means of …