O2 Activation by Metal Surfaces: Implications for Bonding and Reactivity on Heterogeneous Catalysts
The activation of O2 on metal surfaces is a critical process for heterogeneous catalysis and
materials oxidation. Fundamental studies of well-defined metal surfaces using a variety of …
materials oxidation. Fundamental studies of well-defined metal surfaces using a variety of …
Towards operando computational modeling in heterogeneous catalysis
L Grajciar, CJ Heard, AA Bondarenko… - Chemical Society …, 2018 - pubs.rsc.org
An increased synergy between experimental and theoretical investigations in
heterogeneous catalysis has become apparent during the last decade. Experimental work …
heterogeneous catalysis has become apparent during the last decade. Experimental work …
Pd-catalyzed electrohydrogenation of carbon dioxide to formate: high mass activity at low overpotential and identification of the deactivation pathway
Electrochemical reduction of CO2 to formate (HCO2–) powered by renewable electricity is a
possible carbon-negative alternative to synthesizing formate from fossil fuels. This process is …
possible carbon-negative alternative to synthesizing formate from fossil fuels. This process is …
Mechanism for the Direct Synthesis of H2O2 on Pd Clusters: Heterolytic Reaction Pathways at the Liquid–Solid Interface
Direct synthesis (H2+ O2→ H2O2) is a promising reaction for producing H2O2, which can
replace chlorinated oxidants in industrial processes. The mechanism of this reaction and the …
replace chlorinated oxidants in industrial processes. The mechanism of this reaction and the …
[LIVRE][B] Oxygen in catalysis
A Bielanski, J Haber - 1990 - taylorfrancis.com
A description of catalytic systems commonly used as model systems in the laboratory and as
industrial catalysts in large-scale operations, and a discussion of the mechanisms operating …
industrial catalysts in large-scale operations, and a discussion of the mechanisms operating …
Highly active surfaces for CO oxidation on Rh, Pd, and Pt
MS Chen, Y Cai, Z Yan, KK Gath, S Axnanda… - Surface Science, 2007 - Elsevier
Studies show that the rate of CO oxidation on Pt-group metals at temperatures between 450
and 600K and pressures between 1 and 300Torr increases markedly with an increase in the …
and 600K and pressures between 1 and 300Torr increases markedly with an increase in the …
Kinetics of carbon monoxide oxidation on single-crystal palladium, platinum, and iridium
PJ Berlowitz, CHF Peden… - The Journal of Physical …, 1988 - ACS Publications
Introduction The oxidationof CO by 02 over group VIII metal catalysts has beenthe subject of
a large body of ultra-high-vacuum (UHV) surface science and high-pressure catalysis work …
a large body of ultra-high-vacuum (UHV) surface science and high-pressure catalysis work …
Kinetics of PdO combustion catalysis
JG McCarty - Catalysis Today, 1995 - Elsevier
The kinetics of the catalytic combustion of methane by supported palladium oxide catalysts
(2 wt.-% Pd/La2O3· 11A12O3 and 5 wt.-% Pd/γ-A1203 were examined for several oxygen …
(2 wt.-% Pd/La2O3· 11A12O3 and 5 wt.-% Pd/γ-A1203 were examined for several oxygen …
A study of the dynamics of Pd oxidation and PdO reduction by H2and CH4
SC Su, JN Carstens, AT Bell - Journal of Catalysis, 1998 - Elsevier
Palladium is one of the most active catalysts for the catalytic combustion of methane. Since
Pd is oxidized during methane combustion to PdO and PdO is required for high activity, it is …
Pd is oxidized during methane combustion to PdO and PdO is required for high activity, it is …
CO oxidation on Pd (100) and Pd (111): A comparative study of reaction pathways and reactivity at low and medium coverages
CJ Zhang, P Hu - Journal of the American Chemical Society, 2001 - ACS Publications
We have performed density functional theory calculations with the generalized gradient
approximation to investigate CO oxidation on a close-packed transition metal surface, Pd …
approximation to investigate CO oxidation on a close-packed transition metal surface, Pd …