Expanded, contracted, and isomeric porphyrins: Theoretical aspects

J Mack - Chemical Reviews, 2017 - ACS Publications
The use of cyclic polyene perimeter-model approaches, such as Gouterman's four-orbital
model and Michl's perimeter model, to analyze trends in the electronic structures and optical …

Long-Term Stable Organic Solar Cells through Amphiphilic Additives

YT Gerase, J Garcia Lopez… - ACS Applied …, 2024 - ACS Publications
Organic solar cells have recently experienced tremendous efficiency improvements, but their
longevity is still limited by morphological degradation, among other factors. We demonstrate …

Fluorescent pyrene moiety in fluorinated C6F5-corroles increases the interaction with HSA and CT-DNA

TV Acunha, OA Chaves, BA Iglesias - Journal of Porphyrins and …, 2021 - World Scientific
Two fluorinated meso-C6F5-corroles (5, 15-bis (pentafluorophenyl)-10-(phenyl) corrole and
5, 15-bis (pentafluorophenyl)-10-(1-pyrenyl) corrole) were biologically evaluated in terms of …

Photophysical properties of β-substituted free-base corroles

CM Lemon, RL Halbach, M Huynh… - Inorganic …, 2015 - ACS Publications
Corroles are an emergent class of fluorophores that are finding an application and reaction
chemistry to rival their porphyrin analogues. Despite a growing interest in the synthesis …

Tuning Optical Properties of Organic Thin Films through Intermolecular Interactions‐Fundamentals, Advances and Strategies

SJ Finkelmeyer, M Presselt - Chemistry–A European Journal, 2025 - Wiley Online Library
In applications ranging from photon‐energy conversion into electrical or chemical forms
(such as photovoltaics or photocatalysis) to numerous sensor technologies based on …

Quantum chemical insights into the dependence of porphyrin basicity on the meso-aryl substituents: thermodynamics, buckling, reaction sites and molecular flexibility

M Presselt, W Dehaen, W Maes, A Klamt… - Physical Chemistry …, 2015 - pubs.rsc.org
The chemical and sensing properties of porphyrins are frequently tuned via the introduction
of peripheral substituents. In the context of the exceptionally fast second protonation step in …

Molecular structure and conformation of free base corroles

M Wouter - Макрогетероциклы, 2019 - cyberleninka.ru
Corroles represent a unique family of tetrapyrrolic chromophores with distinct structural,
chemical and photophysical properties, which render them promising materials for …

The synthesis and highly effective antibacterial properties of Cu-3, 5-dimethy l-1, 2, 4-triazole metal organic frameworks

X Xu, M Ding, K Liu, F Lv, Y Miao, Y Liu, Y Gong… - Frontiers in …, 2023 - frontiersin.org
The influence of metal ions, the state of metal salt, and ligands on the sterilization ability of
(Metalorganic frameworks) MOFs to effectively achieve sterilization has been investigated in …

Synthesis, photophysical properties and spectroelectrochemical characterization of 10-(4-methyl-bipyridyl)-5, 15-(pentafluorophenyl) corrole

RC Pivetta, BL Auras, B de Souza, A Neves… - … of Photochemistry and …, 2017 - Elsevier
The new bipyridyl-corrole dye 10-(4-methyl-bipyridyl)-5, 15-(pentafluorophenyl) corrole,
encompassing a coordenative methyl-bipyridine moiety (corrole 2), was prepared starting …

MCD and MCPL characterization of luminescent Si (IV) and P (V) tritolylcorroles: the role of coordination number

S Ghidinelli, S Abbate, G Mazzeo, R Paolesse… - ACS …, 2021 - ACS Publications
Two triarylcorrole complexes,(hydroxy)[5, 10, 15-tritolylcorrolato] silicon-(TTC) Si (OH) and
(dihydroxy)[5, 10, 15-tritolylcorrolato] phosphorous-(TTC) P (OH) 2, have been investigated …