Covalent organic frameworks (COFs) for electrochemical applications
Covalent organic frameworks are a class of extended crystalline organic materials that
possess unique architectures with high surface areas and tuneable pore sizes. Since the …
possess unique architectures with high surface areas and tuneable pore sizes. Since the …
Energy-related small molecule activation reactions: oxygen reduction and hydrogen and oxygen evolution reactions catalyzed by porphyrin-and corrole-based …
W Zhang, W Lai, R Cao - Chemical reviews, 2017 - ACS Publications
Globally increasing energy demands and environmental concerns related to the use of fossil
fuels have stimulated extensive research to identify new energy systems and economies that …
fuels have stimulated extensive research to identify new energy systems and economies that …
Recent advances in metal/covalent organic frameworks based materials: Their synthesis, structure design and potential applications for hydrogen production
In recent years, both-organic frameworks (MOFs) based and covalent-organic frameworks
(COFs) based materials have been extensively utilized for catalysis because of their specific …
(COFs) based materials have been extensively utilized for catalysis because of their specific …
A general strategy for decoupled hydrogen production from water splitting by integrating oxidative biomass valorization
Conventional water electrolyzers produce H2 and O2 simultaneously, such that additional
gas separation steps are needed to prevent H2/O2 mixing. The sluggish anodic O2 …
gas separation steps are needed to prevent H2/O2 mixing. The sluggish anodic O2 …
Density functional theory for transition metals and transition metal chemistry
We introduce density functional theory and review recent progress in its application to
transition metal chemistry. Topics covered include local, meta, hybrid, hybrid meta, and …
transition metal chemistry. Topics covered include local, meta, hybrid, hybrid meta, and …
Manganese compounds as water-oxidizing catalysts: from the natural water-oxidizing complex to nanosized manganese oxide structures
All cyanobacteria, algae, and plants use a similar water-oxidizing catalyst for water
oxidation. This catalyst is housed in Photosystem II, a membrane-protein complex that …
oxidation. This catalyst is housed in Photosystem II, a membrane-protein complex that …
P450 Enzymes: Their Structure, Reactivity, and Selectivity Modeled by QM/MM Calculations
The introduction of oxygen into biochemical processes has brought about an evolutionary
leap in the history of life, whereby many organisms have evolved to use oxygen as part of …
leap in the history of life, whereby many organisms have evolved to use oxygen as part of …
Heme and nonheme high-valent iron and manganese oxo cores in biological and abiological oxidation reactions
M Guo, T Corona, K Ray, W Nam - ACS Central Science, 2018 - ACS Publications
Utilization of O2 as an abundant and environmentally benign oxidant is of great interest in
the design of bioinspired synthetic catalytic oxidation systems. Metalloenzymes activate O2 …
the design of bioinspired synthetic catalytic oxidation systems. Metalloenzymes activate O2 …
Chemistry with methane: concepts rather than recipes
H Schwarz - Angewandte Chemie International Edition, 2011 - Wiley Online Library
Four seemingly simple transformations related to the chemistry of methane will be
addressed from mechanistic and conceptual points of view: 1) metal‐mediated …
addressed from mechanistic and conceptual points of view: 1) metal‐mediated …
Beyond iron: non-classical biological functions of bacterial siderophores
TC Johnstone, EM Nolan - Dalton Transactions, 2015 - pubs.rsc.org
Bacteria secrete small molecules known as siderophores to acquire iron from their
surroundings. For over 60 years, investigations into the bioinorganic chemistry of these …
surroundings. For over 60 years, investigations into the bioinorganic chemistry of these …