Transition-metal-catalyzed C–S, C–Se, and C–Te bond formations via cross-coupling and atom-economic addition reactions. Achievements and challenges

IP Beletskaya, VP Ananikov - Chemical Reviews, 2022 - ACS Publications
In the present review, we discuss recent progress in the field of C–Z bond formation
reactions (Z= S, Se, Te) catalyzed by transition metals. Two complementary methodologies …

A fruitful decade of organofluorine chemistry: new reagents and reactions

FL Qing, XY Liu, JA Ma, Q Shen, Q Song… - CCS …, 2022 - chinesechemsoc.org
The development of synthetic methods for the introduction of the fluorine atom and
fluoroalklyl groups into organic molecules has gained increased attention. Synthetic organic …

Einführung von Fluor und fluorhaltigen funktionellen Gruppen

T Liang, CN Neumann, T Ritter - Angewandte Chemie, 2013 - Wiley Online Library
Die wichtigsten konzeptionellen Fortschritt auf dem Gebiet der Fluorierungen der letzten
zehn Jahre wurden durch die Organo‐und Übergangsmetallkatalyse ermöglicht. Die …

Katalytische Funktionalisierung von C (sp2)‐H‐und C (sp3)‐H‐Bindungen unter Verwendung von zweizähnigen dirigierenden Gruppen

G Rouquet, N Chatani - Angewandte Chemie, 2013 - Wiley Online Library
C‐H‐Bindungen sind in organischen Verbindungen allgegenwärtig. Daher erscheint die
direkte Funktionalisierung von Substraten durch Aktivierung von C‐H‐Bindungen als eine …

Bidentate directing groups: an efficient tool in C–H bond functionalization chemistry for the expedient construction of C–C bonds

S Rej, Y Ano, N Chatani - Chemical reviews, 2020 - ACS Publications
During the past decades, synthetic organic chemistry discovered that directing group
assisted C–H activation is a key tool for the expedient and siteselective construction of C–C …

[HTML][HTML] A comprehensive overview of directing groups applied in metal-catalysed C–H functionalisation chemistry

C Sambiagio, D Schönbauer, R Blieck… - Chemical Society …, 2018 - pubs.rsc.org
The present review is devoted to summarizing the recent advances (2015–2017) in the field
of metal-catalysed group-directed C–H functionalisation. In order to clearly showcase the …

First-row transition-metal-catalyzed carbonylative transformations of carbon electrophiles

JB Peng, FP Wu, XF Wu - Chemical reviews, 2018 - ACS Publications
The main contributions in the field of first-row transition-metal-catalyzed (base-metal-
catalyzed) carbonylative transformations have been summarized and discussed. The …

Transition metal-catalyzed C–H bond functionalizations by the use of diverse directing groups

Z Chen, B Wang, J Zhang, W Yu, Z Liu… - Organic Chemistry …, 2015 - pubs.rsc.org
Transition metal-catalyzed direct functionalization of C–H bonds is one of the key emerging
strategies that is currently attracting tremendous attention with the aim to provide alternative …

Bidentate, monoanionic auxiliary-directed functionalization of carbon–hydrogen bonds

O Daugulis, J Roane, LD Tran - Accounts of chemical research, 2015 - ACS Publications
Conspectus In recent years, carbon–hydrogen bond functionalization has evolved from an
organometallic curiosity to a tool used in mainstream applications in the synthesis of …

Synthetic Methods for Compounds Having CF3–S Units on Carbon by Trifluoromethylation, Trifluoromethylthiolation, Triflylation, and Related Reactions

XH Xu, K Matsuzaki, N Shibata - Chemical reviews, 2015 - ACS Publications
1. INTRODUCTION Fluorine is the most abundant halogen in the Earth, s crust. 1 However,
only a dozen fluorinated organic compounds have been identified in nature. 2 Most of the …