An air-stable Dy (III) single-ion magnet with high anisotropy barrier and blocking temperature
Herein we report air-stable Dy (III) and Er (III) single-ion magnets (SIMs) with pseudo-D5h
symmetry, synthesized from a sterically encumbered phosphonamide, tBuPO (NHiPr) 2 …
symmetry, synthesized from a sterically encumbered phosphonamide, tBuPO (NHiPr) 2 …
Nanoscopic molecular magnets
Nanoscopic molecular magnets have attracted tremendous interest in recent years both from
an experimental and a theoretical point of view because of their potential application in …
an experimental and a theoretical point of view because of their potential application in …
Heterometallic 3d–4f single molecule magnets containing diamagnetic metal ions
Molecular nano magnets such as single-molecule magnets (SMMs) are a class of
coordination complexes with numerous potential applications such as information storage …
coordination complexes with numerous potential applications such as information storage …
Role of the Diamagnetic Zinc (II) Ion in Determining the Electronic Structure of Lanthanide Single‐Ion Magnets
Four complexes containing DyIII and PrIII ions and their LnIII–ZnII analogs have been
synthesized in order to study the influence that a diamagnetic ZnII ion has on the electronic …
synthesized in order to study the influence that a diamagnetic ZnII ion has on the electronic …
An unprecedented zero field neodymium (III) single-ion magnet based on a phosphonic diamide
The axial ligation by the–PO group of a phosphonic diamide in an air-stable Nd (III) complex
ensures a pseudo-D5h symmetry leading to the stabilization of the mJ=|±9/2> state; this in …
ensures a pseudo-D5h symmetry leading to the stabilization of the mJ=|±9/2> state; this in …
Heteroatom-modulated assembly of hexalanthanoid-containing polyoxometalate-based coordination networks
ZX Yang, XW Liang, D Lin, Q Zheng, Y Huo - Inorganic Chemistry, 2023 - ACS Publications
Two series of lanthanoid (Ln)-containing polyoxometalates (POMs){[Ln6 (ampH) 4 (H2O) 24–
n (ampH2) n (PW11O39) 2]· 21H2O (Ln= Tb, n= 0 (1), Ln= Er, n= 1 (2)) and K2 [Ln6 (ampH) …
n (ampH2) n (PW11O39) 2]· 21H2O (Ln= Tb, n= 0 (1), Ln= Er, n= 1 (2)) and K2 [Ln6 (ampH) …
Modelling spin Hamiltonian parameters of molecular nanomagnets
T Gupta, G Rajaraman - Chemical Communications, 2016 - pubs.rsc.org
Molecular nanomagnets encompass a wide range of coordination complexes possessing
several potential applications. A formidable challenge in realizing these potential …
several potential applications. A formidable challenge in realizing these potential …
Single‐Molecule Magnetism, Enhanced Magnetocaloric Effect, and Toroidal Magnetic Moments in a Family of Ln4 Squares
Abstract Three cationic [Ln4] squares (Ln= lanthanide) were isolated as single crystals and
their structures solved as [Dy4 (μ4‐OH)(HL)(H2L) 3 (H2O) 4] Cl2⋅(CH3OH) 4⋅(H2O) 8 …
their structures solved as [Dy4 (μ4‐OH)(HL)(H2L) 3 (H2O) 4] Cl2⋅(CH3OH) 4⋅(H2O) 8 …
Towards comparative investigation of Er-and Yb-based SMMs: The effect of the coordination environment configuration on the magnetic relaxation in the series of …
SP Petrosyants, KA Babeshkin, AV Gavrikov… - Dalton …, 2019 - pubs.rsc.org
We prepared and studied two similar series of Er and Yb thiocyanates, involving [Ln (H2O) 5
(NCS) 3]· H2O (1Er, 1Yb) as well as the molecular and ionic complexes with 2, 2 …
(NCS) 3]· H2O (1Er, 1Yb) as well as the molecular and ionic complexes with 2, 2 …
Windmill-like Ln4 Clusters [Ln = Tb(III) and Dy(III)] Bridged by [α-AsW9O33]9– Unit Showing Zero-Field SMM Behavior: Experimental and Theoretical Investigation
Herein, two polyoxometalate (POM)-ligated tetranuclear rare-earth metal complexes having
the molecular formula [Cs x K24–x {Ln4 (H2O) 8 (α-AsW9O33) 4}]· y H2O {x= 5, y= 20, and …
the molecular formula [Cs x K24–x {Ln4 (H2O) 8 (α-AsW9O33) 4}]· y H2O {x= 5, y= 20, and …