Concepts and principles of self-n-do** in perylene diimide chromophores for applications in biochemistry, energy harvesting, energy storage, and catalysis

D Powell, L Whittaker-Brooks - Materials Horizons, 2022 - pubs.rsc.org
Self-do** is an essential method of increasing carrier concentrations in organic
electronics that eliminates the need to tailor host—dopant miscibility, a necessary step when …

Fluorescence-detected circular dichroism of a chiral molecular monolayer with dielectric metasurfaces

ML Solomon, JM Abendroth… - Journal of the …, 2020 - ACS Publications
Strong enhancement of molecular circular dichroism (CD) has the potential to enable
efficient asymmetric photolysis, a method of chiral separation that has conventionally been …

Exploring the mechanism of fluorescence quenching in proteins induced by tetracycline

U Anand, C Jash, RK Boddepalli… - The Journal of …, 2011 - ACS Publications
The binding of the antibiotic tetracycline hydrochloride (TC) to three proteins was
investigated by steady-state, time-resolved, and circular dichroism spectroscopy. The …

Access to triplet excited state in core-twisted perylenediimide

K Nagarajan, AR Mallia, VS Reddy… - The Journal of Physical …, 2016 - ACS Publications
Solvent-free crystal structure of N, N-bis (propylacetyl)-1, 6, 7, 12-tetrabromoperylene-3, 4: 9,
10-bis (dicarboximide), PDI-Br4, obtained by X-ray diffraction reveals the core-twisted …

Tuning exciton coupling of merocyanine nucleoside dimers by RNA, DNA and GNA double helix conformations

J Dietzsch, D Bialas, J Bandorf, F Würthner… - Angewandte …, 2022 - Wiley Online Library
Exciton coupling between two or more chromophores in a specific environment is a key
mechanism associated with color tuning and modulation of absorption energies. This …

Deoxyribonucleic acid encoded and size-defined π-stacking of perylene diimides

J Gorman, SRE Orsborne, A Sridhar… - Journal of the …, 2021 - ACS Publications
Natural photosystems use protein scaffolds to control intermolecular interactions that enable
exciton flow, charge generation, and long-range charge separation. In contrast, there is …

Sculpting photoproducts with DNA origami

J Gorman, SM Hart, T John, MA Castellanos, D Harris… - Chem, 2024 - cell.com
Natural light-harvesting systems spatially organize densely packed dyes in different
configurations to either transport excitons or convert them into charged photoproducts, with …

Formation of Two Homo‐chromophoric H‐Aggregates in DNA‐Assembled Alternating Dye Stacks

CB Winiger, SM Langenegger, G Calzaferri… - Angewandte …, 2015 - Wiley Online Library
The understanding and description of collectively excited multichromophores is of crucial
importance for many areas of basic and applied research. DNA has been used for the …

Exciton‐vibrational couplings in homo‐and heterodimer stacks of Perylene Bisimide dyes within cyclophanes: studies on absorption properties and theoretical …

D Bialas, C Brüning, F Schlosser… - … A European Journal, 2016 - Wiley Online Library
The optical properties of a series of three cyclophanes comprising either identical or different
perylene bisimide (PBI) chromophores were studied by UV/Vis absorption spectroscopy and …

Novel azepino-perylenebisimides: synthesis, structure, and properties

R Mishra, P Panini, J Sankar - Organic letters, 2014 - ACS Publications
The first example of an azepine ring formation by counterintuitive nucleophilic participation
of DBU was observed at the sterically crowded bay area of electron-deficient …