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Activation of epoxides by a cooperative iron–thiolate catalyst: intermediacy of ferrous alkoxides in catalytic hydroboration
This paper describes a cooperative iron–thiolate catalyst Cp* Fe (1, 2-Ph2PC6H4S)(NCMe)(
Cp*–= C5Me5–,[1 (NCMe)]) for regioselective hydroboration of aryl epoxide by …
Cp*–= C5Me5–,[1 (NCMe)]) for regioselective hydroboration of aryl epoxide by …
Unprecedented Borane, Diborane (3), Diborene, and Borylene Ligands via Pt-Mediated Borane Dehydrogenation
Reactions of an aryldihydroborane with a Pt0 complex lead to a range of novel products,
including complexes with bridging diborene and diborane (3) ligands and a complex with …
including complexes with bridging diborene and diborane (3) ligands and a complex with …
Chemistry of Dimetallaoctaborane (12) with Chalcogen-Based Borate Ligands: Obedient versus Disobedient Clusters
The reactions of dimetallaoctaboranes (12)[(Cp* M) 2B6H10][M= Co (1) or Rh (2); Cp*= η5-
C5Me5] with different chalcogen sources, such as Li [BH2E3] and Li [BH3EPh](E= S, Se, or …
C5Me5] with different chalcogen sources, such as Li [BH2E3] and Li [BH3EPh](E= S, Se, or …
Borane polyhedra beyond icosahedron
Polyhedral boron cluster chemistry has been dominated over the last six decades by
icosahedral borate dianions, carboranes, metallacarboranes and metallaboranes owing to …
icosahedral borate dianions, carboranes, metallacarboranes and metallaboranes owing to …
Diborane (6) and Its Analogues Stabilized by Mono-, Bi-, and Trinuclear Group 7 Templates: Combined Experimental and Theoretical Studies
Irradiation of [Re2 (CO) 10] in the presence of BH3· thf resulted in the formation of several
rhenium diborane (6) species, for example,[{(OC) 4Re}{Re (CO) 3} 2 (μ3-η2: η2: η2-B2H6)(μ …
rhenium diborane (6) species, for example,[{(OC) 4Re}{Re (CO) 3} 2 (μ3-η2: η2: η2-B2H6)(μ …
Diborane and Triborane Species in the Coordination Sphere of Group-8 Transition Metals
The synthesis and structural elucidation of a series of ruthenium diborane and triborane
compounds are described. Treatment of [Cp* Ru (PPh3) 2Cl](1)(Cp*= 1, 2, 3, 4, 5 …
compounds are described. Treatment of [Cp* Ru (PPh3) 2Cl](1)(Cp*= 1, 2, 3, 4, 5 …
Structures and Bonding of Early Transition Metallaborane Clusters
Structures and bonding of various homo-and heterometallic metallaborane clusters are
described, which are stabilized in the coordination sphere of early transition metals. For …
described, which are stabilized in the coordination sphere of early transition metals. For …
Synthesis, Structure and Bonding of the Tungstaboranes [Cp*W(CO)2B3H8] and [(Cp*W)3(CO)2B4H7]
The structure and bonding of two novel tungstaboranes which were synthesized using
diverse synthetic methods are described.(i) The room-temperature photolysis of [Cp* W (CO) …
diverse synthetic methods are described.(i) The room-temperature photolysis of [Cp* W (CO) …
Reactions of the phosphinidene-bridged complexes [Fe 2 (η 5-C 5 H 5) 2 (μ-PR)(μ-CO)(CO) 2](R= Cy, Ph) with electrophiles based on p-block elements
The title complexes reacted readily with the methylating agents MeI and CF3SO3Me,
chalcogens (O2, S8) and borane adducts BH3· L (L= THF, NtBu3, PPh3) to initially give the …
chalcogens (O2, S8) and borane adducts BH3· L (L= THF, NtBu3, PPh3) to initially give the …
Cluster fusion: Face-fused macropolyhedral tetracobaltaboranes
In an effort to isolate the 16-vertex supraicosahedral cobaltaborane [(Cp* Co) 3B12H12Co
{Cp* CoB4H9}](Cp*= η5-C5Me5), we have pyrolyzed an in situ generated intermediate …
{Cp* CoB4H9}](Cp*= η5-C5Me5), we have pyrolyzed an in situ generated intermediate …