Schwertmannite: A review of its occurrence, formation, structure, stability and interactions with oxyanions

VA Schoepfer, ED Burton - Earth-Science Reviews, 2021 - Elsevier
In this article, we provide a critical review on the occurrence, formation, structure and stability
of schwertmannite–an enigmatic Fe (III) oxyhydroxy-sulfate mineral that is of widespread …

Iron and sulfur cycling in acid sulfate soil wetlands under dynamic redox conditions: A review

N Karimian, SG Johnston, ED Burton - Chemosphere, 2018 - Elsevier
Acid sulfate soils (ASS) contain substantial quantities of iron sulfide minerals or the oxidation
reaction products of these sulfidic minerals. Transformation of iron (Fe) and sulfur (S) …

Geochemical processes controlling fate and transport of arsenic in acid mine drainage (AMD) and natural systems

H Cheng, Y Hu, J Luo, B Xu, J Zhao - Journal of hazardous materials, 2009 - Elsevier
Acid mine drainage (AMD) is often accompanied with elevated concentrations of arsenic, in
the forms of arsenite, As (III), and/or arsenate, As (V), due to the high affinity of arsenic for …

The effect of silica and natural organic matter on the Fe (II)-catalysed transformation and reactivity of Fe (III) minerals

AM Jones, RN Collins, J Rose, TD Waite - Geochimica et Cosmochimica …, 2009 - Elsevier
The Fe (II)-catalysed transformation of synthetic schwertmannite, ferrihydrite, jarosite and
lepidocrocite to more stable, crystalline Fe (III) oxyhydroxides is prevented by high, natural …

Arsenic mobility during flooding of contaminated soil: the effect of microbial sulfate reduction

ED Burton, SG Johnston, BD Kocar - Environmental science & …, 2014 - ACS Publications
In floodplain soils, As may be released during flooding-induced soil anoxia, with the degree
of mobilization being affected by microbial redox processes such as the reduction of As (V) …

A New Approach for Investigating Iron Mineral Transformations in Soils and Sediments Using 57Fe-Labeled Minerals and 57Fe Mössbauer Spectroscopy

L Notini, K Schulz, LJ Kubeneck… - Environmental …, 2023 - ACS Publications
Iron minerals in soils and sediments play important roles in many biogeochemical processes
and therefore influence the cycling of major and trace elements and the fate of pollutants in …

Sorption of arsenic (V) and arsenic (III) to schwertmannite

ED Burton, RT Bush, SG Johnston… - Environmental …, 2009 - ACS Publications
This study describes the sorption of As (V) and As (III) to schwertmannite as a function of pH
and arsenic loading. In general, sorption of As (V) was greatest at low pH, whereas high pH …

Antimony immobilization mechanism on schwertmannite: Insights from the microstructure of schwertmannite

J Shan, M He, P Liu, W Wang, C Lin, W Ouyang… - … et Cosmochimica Acta, 2023 - Elsevier
Schwertmannite affects the mobility of antimony (Sb) in acid mine drainage, yet the Sb
sorption mechanism remains elusive. In this study, the molecular-level mechanism and the …

Temperature dependence and coupling of iron and arsenic reduction and release during flooding of a contaminated soil

FA Weber, AF Hofacker, A Voegelin… - … science & technology, 2010 - ACS Publications
Arsenic (As) in soils and sediments is commonly mobilized when anoxic conditions promote
microbial iron (Fe) and As reduction. Recent laboratory studies and field observations have …

Arsenic-imposed effects on schwertmannite and jarosite formation in acid mine drainage and coupled impacts on arsenic mobility

ED Burton, N Karimian, SG Johnston… - ACS Earth and Space …, 2021 - ACS Publications
This study explores interactions between As and Fe (III) minerals, predominantly
schwertmannite and jarosite, in acid mine drainage (AMD) via observations at a former mine …