Over the past few years, CuH‐catalyzed hydroamination has been discovered and
developed as a robust and conceptually novel approach for the synthesis of …

Nitrogen-containing compounds, such as amines, enamines, and imines, are valuable and
commercially important bulk chemicals, specialty chemicals, and pharmaceuticals. 1 Among …

The β-diketiminate-stabilized calcium amide complex [{ArNC (Me) CHC (Me) NAr} Ca {N
(SiMe3) 2}(THF)](Ar= 2, 6-diisopropylphenyl) and magnesium methyl complex [{ArNC (Me) …

Chiral 3, 3 '-bis (trisarylsilyl)-substituted binaphtholate rare earth metal complexes (R)-[Ln
{Binol-SiAr3}(o-C6H4CH2NMe2)(Me2NCH2Ph)](Ln= Sc, Lu, Y; Binol-SiAr3= 3, 3 '-bis …

Hydroamination, an atom-economic one-step reaction that refers to the addition of an NH
unit into CC/CX multiple bonds, provides an ideally efficient methodology to construct C–N …

The heavier group 2 complexes [M {N (SiMe3) 2} 2] 2 (1, M= Ca; 2, M= Sr) and [M {CH
(SiMe3) 2} 2 (THF) 2](3, M= Ca; 4, M= Sr) are shown to be effective precatalysts for the …

In this critical review we summarize the latest results obtained during the last decade
concerning the catalytic activities of organoactinide complexes. We begin with a brief …

A mechanistic study of intramolecular hydroamination/cyclization catalyzed by tetravalent
organoactinide and organozirconium complexes is presented. A series of selectively …

Selective amine alkylation: AP, N‐ligand‐stabilized iridium complex has been used as an
efficient catalyst for the alkylation of (hetero) aromatic amines with alcohols at mild reaction …

The additions of various nucleophiles (XeH) to carbonecarbon (CeC) multiple bonds are of
prime importance in synthetic organic chemistry. These essentially simple reactions allow …