Asymmetric catalysis with transition‐metal complexes is the basis for a vast array of
stereoselective transformations and has changed the face of modern synthetic chemistry …

In the past decades there has been a dramatic increase in the demand for enantiopure
compounds for fine-chemicals (ie, agrochemicals and pharmaceuticals) and material …

More than 100 years since its discovery, the mechanism of the Grignard reaction remains
unresolved. Ambiguities arise from the concomitant presence of multiple organomagnesium …

Despite the impressive progress achieved in asymmetric catalysis during the last decade, an
increasing number of new catalysts, ligands, and applications are reported every year to …

Organocopper compounds in organic chemistry appear most frequently in the form of
nucleophilic organocopper (I) reagents, which are used either as stoichiometric reagents or …

Catalytic asymmetric CC bond-forming reactions using organometallic reagents are among
the most important of organic transformations. 1 Frequently, these transformations are key …

There is a need for the preparation of enantiomerically pure compounds for various
applications. An efficient approach to achieve this goal is asymmetric catalysis. The chiral …

A comprehensive overview of recent literature from 2003 concerning advances in
enantioselective copper catalysed 1, 4-addition of organometallic reagents to α, β …

Herein we report the copper-catalyzed silylation of propargylic difluorides to generate axially
chiral, tetrasubstituted monofluoroallenes in both good yields (27 examples> 80%) and …

Herein we describe the enantioselective intermolecular conjugate addition of nitroalkanes to
unactivated α, β‐unsaturated esters, catalyzed by a bifunctional iminophosphorane (BIMP) …