Catalytic partial reduction of N‐heteroarenes with H2 or H [E](E= Si, B‐based) has been a
useful and general method for synthesis of a broad range of dihydropyridines (DHP) and …

Selective reduction of readily available N-heteroarenes is important in both organic
synthesis and chemical biology. Herein, we describe ligand-controlled regiodivergent …

The sterically demanding N-heterocyclic carbene ITr (N, N′-bis (triphenylmethyl)
imidazolylidene) was employed for the preparation of novel trigonal zinc (II) complexes of …

Selective cascading hydroelementation of N-heteroarenes represented by pyridines can
provide diverse accesses to not only dihydro products but also tetrahydro products and …

Judicious designing of ancillary ligands with appropriate stetrolelectronics is critical for the
chemistries of electropositive alkaline earths that typically make labile coordination to …

Low-coordinate heteroleptic zinc hydrides are catalytically important but rare and
synthetically challenging. We herein report three-coordinate monomeric zinc hydride on a 2 …

Exclusive C-donating ligands are rarely used with kinetically labile heavier alkaline earths
(Ca, Sr, Ba). We report herein the aptitude of a combination of NHC with fluorenyl connected …

This work describes the synthesis, characterization and catalytic hydroboration activity of a
family of zinc bis (κ2-borohydride) complexes containing borane-functionalized …

A novel bidentate amine‐imine ligand precursor LH has been synthesized. This compound
was reacted with ZnMe2 to generate the zinc methyl complex, LZnMe (4). The latter …

A series of tri-coordinated zinc alkyl complexes with the general molecular formula [κ2NE-
{NHIRP (Ph)(E) N-Dipp} ZnEt][R= Dipp (2, 6-diisopropylphenyl), E= S (3a), Se (3b) and R …