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Rational design of tapered multiblock copolymers for thermoplastic elastomers
Thermoplastic elastomers (TPEs) combine the features of vulcanized thermoset rubbers and
thermoplastic materials in their phase-separated microdomain structure. As a consequence …
thermoplastic materials in their phase-separated microdomain structure. As a consequence …
Recent developments in synthesis, properties, applications and recycling of bio-based elastomers
In 2021, global plastics production was 390.7 Mt; in 2022, it was 400.3 Mt, showing an
increase of 2.4%, and this rising tendency will increase yearly. Of this data, less than 2 …
increase of 2.4%, and this rising tendency will increase yearly. Of this data, less than 2 …
From terpenes to sustainable and functional polymers
Our dependence on fossil-fuel based raw materials and alarming plastics accumulation in
the environment has inspired many scientists to design and implement more sustainable …
the environment has inspired many scientists to design and implement more sustainable …
Dienes polymerization: Where we are and what lies ahead
G Ricci, G Pampaloni, A Sommazzi, F Masi - Macromolecules, 2021 - ACS Publications
Recently, the research activity in the field of the stereospecific polymerization of conjugated
dienes has focused on the use of catalysts based on organometallic complexes having a …
dienes has focused on the use of catalysts based on organometallic complexes having a …
3D printing of green and renewable polymeric materials: toward greener additive manufacturing
G Guggenbiller, S Brooks, O King… - ACS Applied Polymer …, 2023 - ACS Publications
There is an ever-growing push toward sustainability and green manufacturing in a wide
array of industries, especially 3D printing, which is now recognized as a viable …
array of industries, especially 3D printing, which is now recognized as a viable …
Anionic polymerization of terpene monomers: New options for bio-based thermoplastic elastomers
C Wahlen, H Frey - Macromolecules, 2021 - ACS Publications
Biomass-derived materials possess vast potential for material science and industry in the
next decades. Dwindling fossil resources and an increasing environmental awareness …
next decades. Dwindling fossil resources and an increasing environmental awareness …
[HTML][HTML] Terpenes and terpenoids: building blocks to produce biopolymers
MEG Mosquera, G Jiménez, V Tabernero… - Sustainable …, 2021 - mdpi.com
Polymers are essential materials in our daily life. The synthesis of value-added polymers is
mainly performed from fossil fuel-derived monomers. However, the adoption of the circular …
mainly performed from fossil fuel-derived monomers. However, the adoption of the circular …
Bioderived 4D printable terpene photopolymers from limonene and β-myrcene
E Constant, O King, AC Weems - Biomacromolecules, 2022 - ACS Publications
Green manufacturing and reducing our cultural dependency on petrochemicals have been
topics of growing interest in the past decade, particularly for three-dimensional (3D) …
topics of growing interest in the past decade, particularly for three-dimensional (3D) …
[HTML][HTML] Micro (nano) plastics from synthetic oligomers persisting in Mediterranean seawater: Comprehensive NMR analysis, concerns and origins
The presence in seawater of low-molecular-weight polyethylene (PE) and
polydimethylsiloxane (PDMS), synthetic polymers with high chemical resistance, has been …
polydimethylsiloxane (PDMS), synthetic polymers with high chemical resistance, has been …
Toward more sustainable elastomers: Stereoselective copolymerization of linear terpenes with butadiene
The copolymerization of renewable monomers such as ocimene (O), myrcene (M), and
farnesene (F) with butadiene (B), promoted by dichloro {1, 4-dithiabutanediyl-2, 2′-bis [4, 6 …
farnesene (F) with butadiene (B), promoted by dichloro {1, 4-dithiabutanediyl-2, 2′-bis [4, 6 …