Rational design of tapered multiblock copolymers for thermoplastic elastomers

M Steube, T Johann, RD Barent, AHE Mueller… - Progress in Polymer …, 2022 - Elsevier
Thermoplastic elastomers (TPEs) combine the features of vulcanized thermoset rubbers and
thermoplastic materials in their phase-separated microdomain structure. As a consequence …

Recent developments in synthesis, properties, applications and recycling of bio-based elastomers

M Burelo, A Martínez, JD Hernández-Varela, T Stringer… - Molecules, 2024 - mdpi.com
In 2021, global plastics production was 390.7 Mt; in 2022, it was 400.3 Mt, showing an
increase of 2.4%, and this rising tendency will increase yearly. Of this data, less than 2 …

From terpenes to sustainable and functional polymers

F Della Monica, AW Kleij - Polymer Chemistry, 2020 - pubs.rsc.org
Our dependence on fossil-fuel based raw materials and alarming plastics accumulation in
the environment has inspired many scientists to design and implement more sustainable …

Dienes polymerization: Where we are and what lies ahead

G Ricci, G Pampaloni, A Sommazzi, F Masi - Macromolecules, 2021 - ACS Publications
Recently, the research activity in the field of the stereospecific polymerization of conjugated
dienes has focused on the use of catalysts based on organometallic complexes having a …

3D printing of green and renewable polymeric materials: toward greener additive manufacturing

G Guggenbiller, S Brooks, O King… - ACS Applied Polymer …, 2023 - ACS Publications
There is an ever-growing push toward sustainability and green manufacturing in a wide
array of industries, especially 3D printing, which is now recognized as a viable …

Anionic polymerization of terpene monomers: New options for bio-based thermoplastic elastomers

C Wahlen, H Frey - Macromolecules, 2021 - ACS Publications
Biomass-derived materials possess vast potential for material science and industry in the
next decades. Dwindling fossil resources and an increasing environmental awareness …

[HTML][HTML] Terpenes and terpenoids: building blocks to produce biopolymers

MEG Mosquera, G Jiménez, V Tabernero… - Sustainable …, 2021 - mdpi.com
Polymers are essential materials in our daily life. The synthesis of value-added polymers is
mainly performed from fossil fuel-derived monomers. However, the adoption of the circular …

Bioderived 4D printable terpene photopolymers from limonene and β-myrcene

E Constant, O King, AC Weems - Biomacromolecules, 2022 - ACS Publications
Green manufacturing and reducing our cultural dependency on petrochemicals have been
topics of growing interest in the past decade, particularly for three-dimensional (3D) …

[HTML][HTML] Micro (nano) plastics from synthetic oligomers persisting in Mediterranean seawater: Comprehensive NMR analysis, concerns and origins

A Giannattasio, V Iuliano, G Oliva, D Giaquinto… - Environment …, 2024 - Elsevier
The presence in seawater of low-molecular-weight polyethylene (PE) and
polydimethylsiloxane (PDMS), synthetic polymers with high chemical resistance, has been …

Toward more sustainable elastomers: Stereoselective copolymerization of linear terpenes with butadiene

DH Lamparelli, V Paradiso, FD Monica, A Proto… - …, 2020 - ACS Publications
The copolymerization of renewable monomers such as ocimene (O), myrcene (M), and
farnesene (F) with butadiene (B), promoted by dichloro {1, 4-dithiabutanediyl-2, 2′-bis [4, 6 …