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[HTML][HTML] Carbonation mechanisms and kinetics of lime-based binders: An overview
The reaction of slaked lime with atmospheric CO 2 in the presence of humidity leads to the
formation of cementing carbonate phases in traditional aerial lime mortars and plasters. This …
formation of cementing carbonate phases in traditional aerial lime mortars and plasters. This …
DNA nanostructures as templates for biomineralization
Nature uses extracellular matrix scaffolds to organize biominerals into hierarchical structures
over various length scales. This has inspired the design of biomimetic mineralization …
over various length scales. This has inspired the design of biomimetic mineralization …
New horizons of nonclassical crystallization
Nonclassical crystallization (NCC) summarizes a number of crystallization pathways, which
differ from the classical layer-by-layer growth of crystals involving atomic/molecular building …
differ from the classical layer-by-layer growth of crystals involving atomic/molecular building …
Designing solid materials from their solute state: a shift in paradigms toward a holistic approach in functional materials chemistry
“Non-classical” notions consider formation pathways of crystalline materials where larger
species than monomeric chemical constituents, ie, ions or single molecules, play crucial …
species than monomeric chemical constituents, ie, ions or single molecules, play crucial …
[HTML][HTML] Transformation of amorphous calcium carbonate in the presence of magnesium, phosphate, and mineral surfaces
Amorphous calcium carbonate (ACC) is known as a precursor to crystalline calcium
carbonate polymorphs (CaCO 3) in various natural and synthetic systems. While ACC has …
carbonate polymorphs (CaCO 3) in various natural and synthetic systems. While ACC has …
Phase transformation mechanism of amorphous calcium phosphate to hydroxyapatite investigated by liquid-cell transmission electron microscopy
Crystallization via phase transformation of a metastable precursor is a ubiquitous and
effective strategy used by living systems to direct the growth of crystalline nanomaterials with …
effective strategy used by living systems to direct the growth of crystalline nanomaterials with …
Amorphous and crystalline calcium carbonate phases during carbonation of nanolimes: implications in heritage conservation
Nanolimes are alcohol dispersions of colloidal Ca (OH) 2 nanoparticles used as novel
nanomaterials for the conservation of cultural heritage. Upon exposure to atmospheric CO2 …
nanomaterials for the conservation of cultural heritage. Upon exposure to atmospheric CO2 …
New insights into the nucleation of portlandite and the effects of polymeric additives
The crystallization of calcium hydroxide (Ca (OH) 2, CH, portlandite) is a key process during
the early stages of cement hydration. In the present work, we have revisited the formation of …
the early stages of cement hydration. In the present work, we have revisited the formation of …
Solid‐state transformation of amorphous calcium carbonate to aragonite captured by cryoTEM
Early‐stage reaction mechanisms for aragonite‐promoting systems are relatively unknown
compared to the more thermodynamically stable calcium carbonate polymorph, calcite …
compared to the more thermodynamically stable calcium carbonate polymorph, calcite …
Nonclassical crystallization in vivo et in vitro (II): Nanogranular features in biomimetic minerals disclose a general colloid-mediated crystal growth mechanism
Recent research has shown that biominerals and their biomimetics (i) typically form via an
amorphous precursor phase, and (ii) commonly display a nanogranular texture. Apparently …
amorphous precursor phase, and (ii) commonly display a nanogranular texture. Apparently …