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A field guide to foldamers
The breadth of structure and function displayed by the molecules of biology is remarkable.
Considering that there are only three major biopolymer backbones (proteins, ribonucleic …
Considering that there are only three major biopolymer backbones (proteins, ribonucleic …
Synthetic helical polymers: conformation and function
T Nakano, Y Okamoto - Chemical Reviews, 2001 - ACS Publications
The high functionalities of naturally occurring macromolecules such as proteins and genes
arise from their precisely ordered stereostructures. 1 In such systems, the helix is often found …
arise from their precisely ordered stereostructures. 1 In such systems, the helix is often found …
Amplification of chirality in dynamic supramolecular aggregates
The quest to understand the origin of chirality in biological systems has evoked an intense
search for nonlinear effects in catalysis and pathways to amplify slight enantiomeric …
search for nonlinear effects in catalysis and pathways to amplify slight enantiomeric …
Self‐assembling organic nanotubes
Hollow tubular structures of molecular dimensions perform diverse biological functions in
nature. Examples include scaffolding and packaging roles played by cytoskeletal …
nature. Examples include scaffolding and packaging roles played by cytoskeletal …
Chiral architectures from macromolecular building blocks
In the course of evolution, Nature has developed a multitude of biomacromolecules tailored
to deal with complicated tasks such as information storage, support of tissue, transport, and …
to deal with complicated tasks such as information storage, support of tissue, transport, and …
Helical self-assembled polymers from cooperative stacking of hydrogen-bonded pairs
The double helix of DNA epitomizes this molecule's ability to self-assemble in aqueous
solutions into a complex chiral structure using hydrogen bonding and hydrophobic …
solutions into a complex chiral structure using hydrogen bonding and hydrophobic …
Simultaneous covalent and noncovalent hybrid polymerizations
Covalent and supramolecular polymers are two distinct forms of soft matter, composed of
long chains of covalently and noncovalently linked structural units, respectively. We report a …
long chains of covalently and noncovalently linked structural units, respectively. We report a …
Chiroptical regulation of macrocyclic arenes with flip**-induced inversion of planar chirality
Studies on various macrocyclic arenes have received increasing attention due to their
straightforward syntheses, convenient derivatization, and unique complexation properties …
straightforward syntheses, convenient derivatization, and unique complexation properties …
Supramolecular helices: chirality transfer from conjugated molecules to structures
Y Yang, Y Zhang, Z Wei - Advanced Materials, 2013 - Wiley Online Library
Different scales of chirality endow a material with many excellent properties and potential
applications. In this review, using π‐conjugated molecules as functional building blocks …
applications. In this review, using π‐conjugated molecules as functional building blocks …
Synthesis, characterization, and optical properties of monodisperse chiral oligofluorenes
Y Geng, A Trajkovska, D Katsis, JJ Ou… - Journal of the …, 2002 - ACS Publications
The first series of monodisperse chiral oligofluorenes was synthesized and characterized.
Chain length was found to play an important role in solid morphology. Whereas dimer …
Chain length was found to play an important role in solid morphology. Whereas dimer …