Ion dissociation in ionic liquids and ionic liquid solutions

O Nordness, JF Brennecke - Chemical Reviews, 2020 - ACS Publications
The extent to which cations and anions in ionic liquids (ILs) and ionic liquid solutions are
dissociated is of both fundamental scientific interest and practical importance because ion …

The peculiar effect of water on ionic liquids and deep eutectic solvents

C Ma, A Laaksonen, C Liu, X Lu, X Ji - Chemical Society Reviews, 2018 - pubs.rsc.org
Ionic liquids (ILs) and deep eutectic solvents (DESs) have been suggested as eco-friendly
alternatives to organic solvents. A trace amount of water is often unavoidable as impurity …

Water binding and hygroscopicity in π-conjugated polyelectrolytes

CG Tang, MN Syafiqah, QM Koh, MCY Ang… - Nature …, 2023 - nature.com
The presence of water strongly influences structure, dynamics and properties of ion-
containing soft matter. Yet, the hydration of such matter is not well understood. Here, we …

[HTML][HTML] EMIMBF4 in ternary liquid mixtures of water, dimethyl sulfoxide and acetonitrile as “tri-solvent-in-salt” electrolytes for high-performance supercapacitors …

X Lu, JM Vicent-Luna, S Calero… - Energy Storage …, 2021 - Elsevier
For many years, the performance of Li-ion batteries (LIBs) and supercapacitors (SCs) has
relied mainly on two factors,(1) the optimization of electrodes composition and/or structure …

Properties of water confined in ionic liquids

K Saihara, Y Yoshimura, S Ohta, A Shimizu - Scientific reports, 2015 - nature.com
The varying states of water confined in the nano-domain structures of typical room
temperature ionic liquids (ILs) were investigated by 1H NMR and by measurements of self …

OH stretching and libration bands of solitary water in ionic liquids and dipolar solvents share a single dependence on solvent polarity

K Mukherjee, S Palchowdhury… - The Journal of Physical …, 2022 - ACS Publications
Ionic liquids are an emerging class of materials which are finding application in a variety of
technologically important areas. Because of their hydrophilic character, at least a small …

Cosolvent or antisolvent? A molecular view of the interface between ionic liquids and cellulose upon addition of another molecular solvent

F Huo, Z Liu, W Wang - The Journal of Physical Chemistry B, 2013 - ACS Publications
Ionic liquids (ILs) are promising nonderivatizing solvents for the dissolution of cellulose and
lignin in biomass pretreatment processes, which are, however, retarded by sluggish …

Solid state ionics enabled ultra-sensitive detection of thermal trace with 0.001 K resolution in deep sea

Y Zhang, D Ye, M Li, X Zhang, C Di, C Wang - Nature Communications, 2023 - nature.com
The deep sea remains the largest uncharted territory on Earth because it's eternally dark
under high pressure and the saltwater is corrosive and conductive. The harsh environment …

Atomistic insight into orthoborate-based ionic liquids: force field development and evaluation

YL Wang, FU Shah, S Glavatskih… - The Journal of …, 2014 - ACS Publications
We have developed an all-atomistic force field for a new class of halogen-free chelated
orthoborate-phosphonium ionic liquids. The force field is based on an AMBER framework …

Thiocyanate as a local probe of ultrafast structure and dynamics in imidazolium-based ionic liquids: Water-induced heterogeneity and cation-induced ion pairing

Z Ren, T Brinzer, S Dutta… - The Journal of Physical …, 2015 - ACS Publications
Ultrafast two-dimensional infrared spectroscopy (2D-IR) of thiocyanate ([SCN]−) in 1-butyl-3-
methylimidazolium bis (trifluoromethylsulfonyl) imide ([C4C1im][NTf2]) and 1-butyl-2, 3 …