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Ion dissociation in ionic liquids and ionic liquid solutions
O Nordness, JF Brennecke - Chemical Reviews, 2020 - ACS Publications
The extent to which cations and anions in ionic liquids (ILs) and ionic liquid solutions are
dissociated is of both fundamental scientific interest and practical importance because ion …
dissociated is of both fundamental scientific interest and practical importance because ion …
The peculiar effect of water on ionic liquids and deep eutectic solvents
Ionic liquids (ILs) and deep eutectic solvents (DESs) have been suggested as eco-friendly
alternatives to organic solvents. A trace amount of water is often unavoidable as impurity …
alternatives to organic solvents. A trace amount of water is often unavoidable as impurity …
Water binding and hygroscopicity in π-conjugated polyelectrolytes
The presence of water strongly influences structure, dynamics and properties of ion-
containing soft matter. Yet, the hydration of such matter is not well understood. Here, we …
containing soft matter. Yet, the hydration of such matter is not well understood. Here, we …
[HTML][HTML] EMIMBF4 in ternary liquid mixtures of water, dimethyl sulfoxide and acetonitrile as “tri-solvent-in-salt” electrolytes for high-performance supercapacitors …
For many years, the performance of Li-ion batteries (LIBs) and supercapacitors (SCs) has
relied mainly on two factors,(1) the optimization of electrodes composition and/or structure …
relied mainly on two factors,(1) the optimization of electrodes composition and/or structure …
Properties of water confined in ionic liquids
K Saihara, Y Yoshimura, S Ohta, A Shimizu - Scientific reports, 2015 - nature.com
The varying states of water confined in the nano-domain structures of typical room
temperature ionic liquids (ILs) were investigated by 1H NMR and by measurements of self …
temperature ionic liquids (ILs) were investigated by 1H NMR and by measurements of self …
OH stretching and libration bands of solitary water in ionic liquids and dipolar solvents share a single dependence on solvent polarity
K Mukherjee, S Palchowdhury… - The Journal of Physical …, 2022 - ACS Publications
Ionic liquids are an emerging class of materials which are finding application in a variety of
technologically important areas. Because of their hydrophilic character, at least a small …
technologically important areas. Because of their hydrophilic character, at least a small …
Cosolvent or antisolvent? A molecular view of the interface between ionic liquids and cellulose upon addition of another molecular solvent
Ionic liquids (ILs) are promising nonderivatizing solvents for the dissolution of cellulose and
lignin in biomass pretreatment processes, which are, however, retarded by sluggish …
lignin in biomass pretreatment processes, which are, however, retarded by sluggish …
Solid state ionics enabled ultra-sensitive detection of thermal trace with 0.001 K resolution in deep sea
The deep sea remains the largest uncharted territory on Earth because it's eternally dark
under high pressure and the saltwater is corrosive and conductive. The harsh environment …
under high pressure and the saltwater is corrosive and conductive. The harsh environment …
Atomistic insight into orthoborate-based ionic liquids: force field development and evaluation
We have developed an all-atomistic force field for a new class of halogen-free chelated
orthoborate-phosphonium ionic liquids. The force field is based on an AMBER framework …
orthoborate-phosphonium ionic liquids. The force field is based on an AMBER framework …
Thiocyanate as a local probe of ultrafast structure and dynamics in imidazolium-based ionic liquids: Water-induced heterogeneity and cation-induced ion pairing
Ultrafast two-dimensional infrared spectroscopy (2D-IR) of thiocyanate ([SCN]−) in 1-butyl-3-
methylimidazolium bis (trifluoromethylsulfonyl) imide ([C4C1im][NTf2]) and 1-butyl-2, 3 …
methylimidazolium bis (trifluoromethylsulfonyl) imide ([C4C1im][NTf2]) and 1-butyl-2, 3 …