Uranium complexes can be stabilized in a wide range of oxidation states, ranging from UII to
UVI and a very recent example of a UI complex. This review provides a comprehensive …

One of the most intensely studied areas of f-block chemistry is the nature of the bonds
between the f-element and another species, and in particular the role played by covalency …

There is long-standing interest in nonaqueous uranium chemistry because of fundamental
questions about uranium's variable chemical bonding and the similarities of this pseudo …

The first structurally characterized organometallic multidecker sandwich complexes featuring
a cycloheptatrienyl ring (Cht, C7H73–) in the coordination sphere are presented. The …

Research on actinide materials, both basic and applied, has been greatly advanced by the
general techniques available from high-intensity photon beams from x-ray synchrotron …

Restricted active space simulations are shown to accurately reproduce and characterise
both O K-edge and U M4, 5-edge spectra of uranyl in excellent agreement with experimental …

Chlorine K-edge X-ray absorption near edge structure (XANES) in actinideIV
hexachlorides,[AnCl6] 2−(An= Th–Pu), is calculated with relativistic multiconfiguration …

The reaction of 1 equiv of 1-azidoadamantane with [UIII (NR2) 3](R= SiMe3) in Et2O results
in the formation of [UV (NR2) 3 (NAd)](1, Ad= 1-adamantyl) in good yields. The electronic …

X-ray absorption near edge structure (XANES) spectroscopy, coupled with ab initio
calculations, has emerged as the state-of-the-art tool for elucidating the metal-ligand …

A RASSCF approach to simulate the O K-edge XANES spectra of uranyl is employed,
utilizing three models that progressively improve the representation of the local crystal …