P-Stereogenic phosphorus ligands in asymmetric catalysis
T Imamoto - Chemical reviews, 2024 - ACS Publications
Chiral phosphorus ligands play a crucial role in asymmetric catalysis for the efficient
synthesis of useful optically active compounds. They are largely categorized into two …
synthesis of useful optically active compounds. They are largely categorized into two …
Recent advances in asymmetric borylation by transition metal catalysis
J Hu, M Ferger, Z Shi, TB Marder - Chemical Society Reviews, 2021 - pubs.rsc.org
Chiral organoboronates have played a critical role in organic chemistry and in the
development of materials science and pharmaceuticals. Much effort has been devoted to …
development of materials science and pharmaceuticals. Much effort has been devoted to …
Recent strategies in the nucleophilic dearomatization of pyridines, quinolines, and isoquinolines
M Escolano, D Gaviña, G Alzuet-Piña… - Chemical …, 2024 - ACS Publications
Dearomatization reactions have become fundamental chemical transformations in organic
synthesis since they allow for the generation of three-dimensional complexity from two …
synthesis since they allow for the generation of three-dimensional complexity from two …
Progress in the Chemistry of Tetrahydroquinolines
Tetrahydroquinoline is one of the most important simple nitrogen heterocycles, being
widespread in nature and present in a broad variety of pharmacologically active …
widespread in nature and present in a broad variety of pharmacologically active …
Copper-boryl mediated organic synthesis
Organoboron compounds are valuable synthetic intermediates that find application in a
diverse variety of processes including both C–X and C–C bond-forming transformations …
diverse variety of processes including both C–X and C–C bond-forming transformations …
Asymmetric synthesis of secondary and tertiary boronic esters
BSL Collins, CM Wilson, EL Myers… - Angewandte Chemie …, 2017 - Wiley Online Library
Non‐racemic chiral boronic esters are recognised as immensely valuable building blocks in
modern organic synthesis. Their stereospecific transformation into a variety of functional …
modern organic synthesis. Their stereospecific transformation into a variety of functional …
Rhodium-Catalyzed Double Hydroboration of Quinolines
Selective double hydroelementation of N-heteroarenes can be one of the most
straightforward and atom-economic routes toward dearomatized N-heterocycles bearing a …
straightforward and atom-economic routes toward dearomatized N-heterocycles bearing a …
Asymmetric synthesis of flavanols via Cu-catalyzed kinetic resolution of chromenes and their anti-inflammatory activity
Flavanols are privileged heterocyclic compounds in medicinal chemistry. It is notable to
develop an efficient and straightforward protocol for accessing chiral flavanols with precise …
develop an efficient and straightforward protocol for accessing chiral flavanols with precise …
Dearomative triple elementalization of quinolines driven by visible light
S Ishigaki, Y Nagashima, D Yukimori, J Tanaka… - Nature …, 2023 - nature.com
Organoboron and organosilicon compounds are used not only as synthetic building blocks
but also as functional materials and pharmaceuticals, and compounds with multiple boryl …
but also as functional materials and pharmaceuticals, and compounds with multiple boryl …
Enantiodivergent synthesis of chiral tetrahydroquinoline derivatives via Ir-catalyzed asymmetric hydrogenation: Solvent-dependent enantioselective control and …
Z Han, G Liu, X Yang, XQ Dong, X Zhang - ACS Catalysis, 2021 - ACS Publications
Ir-catalyzed asymmetric hydrogenation of quinolines was developed, and both enantiomers
of chiral tetrahydroquinoline derivatives could be easily obtained, respectively, in high yields …
of chiral tetrahydroquinoline derivatives could be easily obtained, respectively, in high yields …