Benzo-extended heli (aminoborane) s: Inner rim BN-doped helical molecular carbons with remarkable chiroptical properties
Atomically precise synthesis of three-dimensional boron–nitrogen (BN)-based helical
structures constitutes an undeveloped field with challenges in synthetic chemistry. Herein …
structures constitutes an undeveloped field with challenges in synthetic chemistry. Herein …
Boron-and nitrogen-embedded polycyclic arenes as an emerging class of organic semiconductors
The development of novel organic semiconductors has continuously promoted the field of
organic optoelectronics. During the past decade, boron-and nitrogen-embedded (BN …
organic optoelectronics. During the past decade, boron-and nitrogen-embedded (BN …
Intramolecular Alkyne Aromatization: Unexpected Synthesis of Expanded [9] Helicene and π‐Extended Double [4] Helicene, and Their Molecular Geometry Effect on …
Intramolecular alkyne aromatization is a powerful tool that enables the synthesis of
nonplanar polycyclic aromatic hydrocarbons. Herein, an unexpected intramolecular alkyne …
nonplanar polycyclic aromatic hydrocarbons. Herein, an unexpected intramolecular alkyne …
BN-Embedded Cycloarenes: One-Pot Borylation Synthesis, Photoelectric Properties, and Application in Perovskite Solar Cells
Incorporating heteroatoms, such as nitrogen, oxygen, and/or sulfur atoms, into cycloarenes
can effectively regulate their molecular geometries and (opto) electronic properties …
can effectively regulate their molecular geometries and (opto) electronic properties …
Rational Control of Maximum EMI/CPL Intensity and Wavelength of Bora [6] helicene via Polarity and Vibronic Effects
Y Liu, Q Xu, L Wang, A Gao, Q Li, S Chen… - The Journal of …, 2024 - ACS Publications
Solvent polarity control as an efficient methodology to regulate the chiroptical properties,
including spectral shape, width, intensity, wavelength, etc., has emerged as a novel frontier …
including spectral shape, width, intensity, wavelength, etc., has emerged as a novel frontier …
Synthesis of quadruply boron-doped acenes with stimuli-responsive multicolor emission
C Chen, Y Guo, Z Chang, K Müllen… - Nature Communications, 2024 - nature.com
Boron-doped acenes have attracted attention due to their unique structures and intriguing
luminescent properties. However, the hitherto known boron-doped acenes have only one or …
luminescent properties. However, the hitherto known boron-doped acenes have only one or …
Nonalternant Nanographenes Containing N-Centered Cyclopenta[ef]heptalene and Aza[7]Helicene Units
S Qiu, AC Valdivia, W Zhuang, FF Hung… - Journal of the …, 2024 - ACS Publications
Introducing helical subunits into negatively curved π-systems has a significant effect on both
the molecular geometry and photophysical properties; however, the synthesis of these …
the molecular geometry and photophysical properties; however, the synthesis of these …
A theoretical study on application of BN/CC isosterism to modify topology of coronene aromaticity and HOMO–LUMO energy gaps
M Baranac-Stojanović, M Stojanović… - New Journal of …, 2024 - pubs.rsc.org
The change in local, semi-local and peripheral aromaticity of coronene upon gradual
replacement of its peripheral CC bonds with BN bonds, starting from the C3h symmetrical 3 …
replacement of its peripheral CC bonds with BN bonds, starting from the C3h symmetrical 3 …
BN‐Acene Ladder with Enhanced Charge Transport for Organic Field‐Effect Transistors
C Li, Y Sun, N Xue, Y Guo, R Jiang… - Angewandte Chemie …, 2025 - Wiley Online Library
The in‐depth research on the charge transport properties of BN‐embedded polycyclic
aromatic hydrocarbons (BN‐PAHs) still lags far behind studies of their emitting properties …
aromatic hydrocarbons (BN‐PAHs) still lags far behind studies of their emitting properties …
Tetraazahexacene Diimides with Ultralow Lowest Unoccupied Molecular Orbital Levels
S Qiu, L Zhang, X **, C Zhao, J Liu, DH Qu… - CCS …, 2025 - chinesechemsoc.org
Azaacene diimides are expected to possess deep lowest unoccupied molecular orbital
(LUMO) levels and narrower bandgaps while maintaining excellent solubility and enhanced …
(LUMO) levels and narrower bandgaps while maintaining excellent solubility and enhanced …