Nonlinear optical properties of transition metal acetylides and their derivatives

CE Powell, MG Humphrey - Coordination Chemistry Reviews, 2004 - Elsevier
The nonlinear optical (NLO) properties of metal acetylide and vinylidene complexes are
summarized, and molecular structure–NLO property trends are developed. The origin of …

Charge delocalization vs localization in carbon-rich iron mixed-valence complexes: A subtle interplay between the carbon spacer and the (dppe) Cp* Fe …

JF Halet, C Lapinte - Coordination Chemistry Reviews, 2013 - Elsevier
In this review, the electronic and structural properties of different organometallic wires
containing the (dppe) Cp* Fe organometallic electrophore are thoroughly discussed. Results …

Three-dimensional nonlinear optical chromophores based on metal-to-ligand charge-transfer from ruthenium (II) or iron (II) centers

BJ Coe, JA Harris, BS Brunschwig… - Journal of the …, 2005 - ACS Publications
In this article, we describe a series of new complex salts in which electron-rich transition-
metal centers are coordinated to three electron-accepting N-methyl/aryl-2, 2 ': 4, 4 '': 4 ', 4 ''' …

Organotransition metal complexes for nonlinear optics

JP Morrall, GT Dalton, MG Humphrey… - Advances in …, 2007 - Elsevier
Publisher Summary This chapter describes the structure and nonlinear optical (NLO)
property relationships for organometallic systems. Both quadratic and cubic molecular …

Metal complexes for molecular electronics and photonics

BJ Coe, NRM Curati - Comments on Inorganic Chemistry, 2004 - Taylor & Francis
Within the fields of coordination and organometallic chemistry there has recently been much
interest in the design, synthesis and study of novel complexes having potential for …

Bonding and substituent effects in electron-rich mononuclear ruthenium σ-Arylacetylides of the formula [(η2-dppe)(η5-C5Me5) Ru (C⋮ C)-1, 4-(C6H4) X][PF6] n (n= 0 …

F Paul, BG Ellis, MI Bruce, L Toupet, T Roisnel… - …, 2006 - ACS Publications
This study reports the isolation and the structural (X-ray), UV− vis, and NMR characterization
of a series of electron-rich Ru (II) acetylide complexes of the formula (η2-dppe)(η5-C5Me5) …

DFT Studies on the Carboxylation of Arylboronate Esters with CO2 Catalyzed by Copper(I) Complexes

L Dang, Z Lin, TB Marder - Organometallics, 2010 - ACS Publications
DFT calculations have been carried out to study the carboxylation reactions of arylboronate
esters with CO2 catalyzed by (NHC) Cu (I) complexes (NHC= N-heterocyclic carbene). The …

Ruthenium Complexes of C,C'-Bis(ethynyl)carboranes:  An Investigation of Electronic Interactions Mediated by Spherical Pseudo-aromatic Spacers

MA Fox, RL Roberts, TE Baines… - Journal of the …, 2008 - ACS Publications
The complexes [Ru (1-C⋮ C− 1, 10-C2B8H9)(dppe) Cp*](3a),[Ru (1-C⋮ C− 1, 12-
C2B10H11)(dppe) Cp*](3b),[{Ru (dppe) Cp*} 2 {μ-1, 10−(C⋮ C) 2− 1, 10-C2B8H8}](4a) and …

Alkynyl compounds and nonlinear optics

MP Cifuentes, MG Humphrey - Journal of organometallic chemistry, 2004 - Elsevier
The authors' studies of the nonlinear optical (NLO) properties of metal alkynyl complexes are
summarized; structure–NLO property relationships are developed and attempts to “switch” …

Computational studies of the nonlinear optical properties of organometallic complexes

MS Kodikara, R Stranger, MG Humphrey - Coordination Chemistry Reviews, 2018 - Elsevier
Computational methods for calculating the molecular nonlinear optical (NLO) properties of
molecules are reviewed, with an emphasis on clarifying the strengths and weaknesses of …