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Nonlinear optical properties of transition metal acetylides and their derivatives
The nonlinear optical (NLO) properties of metal acetylide and vinylidene complexes are
summarized, and molecular structure–NLO property trends are developed. The origin of …
summarized, and molecular structure–NLO property trends are developed. The origin of …
Charge delocalization vs localization in carbon-rich iron mixed-valence complexes: A subtle interplay between the carbon spacer and the (dppe) Cp* Fe …
JF Halet, C Lapinte - Coordination Chemistry Reviews, 2013 - Elsevier
In this review, the electronic and structural properties of different organometallic wires
containing the (dppe) Cp* Fe organometallic electrophore are thoroughly discussed. Results …
containing the (dppe) Cp* Fe organometallic electrophore are thoroughly discussed. Results …
Three-dimensional nonlinear optical chromophores based on metal-to-ligand charge-transfer from ruthenium (II) or iron (II) centers
In this article, we describe a series of new complex salts in which electron-rich transition-
metal centers are coordinated to three electron-accepting N-methyl/aryl-2, 2 ': 4, 4 '': 4 ', 4 ''' …
metal centers are coordinated to three electron-accepting N-methyl/aryl-2, 2 ': 4, 4 '': 4 ', 4 ''' …
Organotransition metal complexes for nonlinear optics
JP Morrall, GT Dalton, MG Humphrey… - Advances in …, 2007 - Elsevier
Publisher Summary This chapter describes the structure and nonlinear optical (NLO)
property relationships for organometallic systems. Both quadratic and cubic molecular …
property relationships for organometallic systems. Both quadratic and cubic molecular …
Metal complexes for molecular electronics and photonics
BJ Coe, NRM Curati - Comments on Inorganic Chemistry, 2004 - Taylor & Francis
Within the fields of coordination and organometallic chemistry there has recently been much
interest in the design, synthesis and study of novel complexes having potential for …
interest in the design, synthesis and study of novel complexes having potential for …
Bonding and substituent effects in electron-rich mononuclear ruthenium σ-Arylacetylides of the formula [(η2-dppe)(η5-C5Me5) Ru (C⋮ C)-1, 4-(C6H4) X][PF6] n (n= 0 …
This study reports the isolation and the structural (X-ray), UV− vis, and NMR characterization
of a series of electron-rich Ru (II) acetylide complexes of the formula (η2-dppe)(η5-C5Me5) …
of a series of electron-rich Ru (II) acetylide complexes of the formula (η2-dppe)(η5-C5Me5) …
DFT Studies on the Carboxylation of Arylboronate Esters with CO2 Catalyzed by Copper(I) Complexes
L Dang, Z Lin, TB Marder - Organometallics, 2010 - ACS Publications
DFT calculations have been carried out to study the carboxylation reactions of arylboronate
esters with CO2 catalyzed by (NHC) Cu (I) complexes (NHC= N-heterocyclic carbene). The …
esters with CO2 catalyzed by (NHC) Cu (I) complexes (NHC= N-heterocyclic carbene). The …
Ruthenium Complexes of C,C'-Bis(ethynyl)carboranes: An Investigation of Electronic Interactions Mediated by Spherical Pseudo-aromatic Spacers
MA Fox, RL Roberts, TE Baines… - Journal of the …, 2008 - ACS Publications
The complexes [Ru (1-C⋮ C− 1, 10-C2B8H9)(dppe) Cp*](3a),[Ru (1-C⋮ C− 1, 12-
C2B10H11)(dppe) Cp*](3b),[{Ru (dppe) Cp*} 2 {μ-1, 10−(C⋮ C) 2− 1, 10-C2B8H8}](4a) and …
C2B10H11)(dppe) Cp*](3b),[{Ru (dppe) Cp*} 2 {μ-1, 10−(C⋮ C) 2− 1, 10-C2B8H8}](4a) and …
Alkynyl compounds and nonlinear optics
The authors' studies of the nonlinear optical (NLO) properties of metal alkynyl complexes are
summarized; structure–NLO property relationships are developed and attempts to “switch” …
summarized; structure–NLO property relationships are developed and attempts to “switch” …
Computational studies of the nonlinear optical properties of organometallic complexes
Computational methods for calculating the molecular nonlinear optical (NLO) properties of
molecules are reviewed, with an emphasis on clarifying the strengths and weaknesses of …
molecules are reviewed, with an emphasis on clarifying the strengths and weaknesses of …