Amorphous iron fluorosulfate as a high-capacity cathode utilizing combined intercalation and conversion reactions with unexpectedly high reversibility

J Heo, SK Jung, I Hwang, SP Cho, D Eum, H Park… - Nature Energy, 2023 - nature.com
To achieve the desirable dual characteristics of high-capacity performance and low-cost
production for the batteries of tomorrow, leveraging of multi-redox reactions of Earth …

Revealing solid electrolyte interphase formation through interface-sensitive Operando X-ray absorption spectroscopy

JEN Swallow, MW Fraser, NJH Kneusels… - Nature …, 2022 - nature.com
The solid electrolyte interphase (SEI) that forms on Li-ion battery anodes is critical to their
long-term performance, however observing SEI formation processes at the buried electrode …

Spectroscopic fingerprints of valence and spin states in manganese oxides and fluorides

R Qiao, T Chin, SJ Harris, S Yan, W Yang - Current Applied Physics, 2013 - Elsevier
We performed a systematic study of soft X-ray absorption spectroscopy in various
manganese oxides and fluorides. Both Mn L-edges and ligand (O and F) K-edges are …

Unlocking lithium ion conduction in lithium metal fluorides

L Qian, B Singh, Z Yu, N Chen, G King, Z Arthur… - Matter, 2024 - cell.com
Here, we demonstrate that quasi-crystalline lithium metal fluoride materials prepared by
mechanochemical synthesis exhibit up to 300-fold higher ionic conductivity than their …

Soft X-ray ptychography chemical imaging of degradation in a composite surface-reconstructed Li-rich cathode

T Sun, G Sun, F Yu, Y Mao, R Tai, X Zhang, G Shao… - ACS …, 2020 - ACS Publications
The capability in spatially resolving the interactions between components in lithium (Li)-ion
battery cathodes, especially correlating chemistry and electronic structure, is challenging but …

Defect-rich engineering and F dopant Co-modulated NiO hollow dendritic skeleton as a self-supported electrode for high-current density hydrogen evolution reaction

F Zhang, R Ji, Y Liu, Z Li, Z Liu, S Lu, Y Wang… - Chemical Engineering …, 2020 - Elsevier
Exploring the low-cost and high-efficient electrocatalysts with Pt-like activity for alkaline
hydrogen evolution through water splitting is imperative yet challenging. Herein, a simple …

Dynamic evolution of Cathode− Electrolyte interface of LiNi0. 6Co0. 2Mn0. 2O2 during the initial Charge− Discharge process

S Liu, L Wang, C Zhang, B Chu, C Wang… - Journal of Power …, 2019 - Elsevier
The cathode− electrolyte interface (CEI) is a key factor that affects the electrochemical
performance of lithium-ion batteries. However, considerable ambiguity still exists with regard …

EELS spectroscopy of iron fluorides and FeFx/C nanocomposite electrodes used in Li-ion batteries

F Cosandey, JF Al-Sharab, F Badway… - Microscopy and …, 2007 - cambridge.org
A new type of positive electrode for Li-ion batteries has been developed recently based on
FeF3/C and FeF2/C nanocomposites. The microstructural and redox evolution during …

Interaction between single walled carbon nanotube and 1D crystal in CuX@ SWCNT (X= Cl, Br, I) nanostructures

AA Eliseev, LV Yashina, NI Verbitskiy… - Carbon, 2012 - Elsevier
CuX@ SWCNT (X= Cl, Br, I) nanostructures were prepared by capillary filling of 1.4–1.6 nm
single-walled carbon nanotubes (SWCNT) with copper halides. The structure of CuX …

How fluorine introduction solves the spinel transition, a fundamental problem of Mn-based positive electrodes

Y Mahara, N Nagasako, H Oka, Y Kondo… - … Applied Materials & …, 2022 - ACS Publications
In pursuit of high-capacity Mn-based oxides as positive electrode materials for lithium-ion
batteries, the changes in the charge–discharge curve due to the spinel transition still stand …