Abstract Space charge transfer of heterostructures driven by the work‐function‐induced built‐
in field can regulate the electronic structure of catalysts and boost the catalytic activity …

Isolable singlet carbenes have universally adopted a σ2π0 electronic state, making them σ-
donors and π-acceptors. We present a rhodium-coordinated, cationic cyclic …

Exploring new lanthanide metallacycles and finding their unique chemistry different from the
analogues of transition metals are of great interest and importance. In this work, we reported …

Complexes with ligand-to-metal charge-transfer (LMCT) excited states involving d0 metals
represent a new design for photocatalysts. Herein, the photochemistry and photophysics of …

The synthesis, electronic structure, and reactivity of a uranium metallacyclopropene were
comprehensively studied. Addition of diphenylacetylene (PhC≡ CPh) to the uranium …

A new concept for obtaining cationic complexes with triflate counteranions from coordinating
triflato ligands was developed. Various routes are leading to titanium (IV) and titanium (III) …

This feature article highlights the discovery and development of phosphanoxyl complex
chemistry starting from (neutral) low-coordinate phosphorus radicals and the quest of metal …

The phospha–Wittig reagent MesTerPPMe3 (MesTer= 2, 6-{2, 4, 6-Me3–C6H2}–C6H3) and
arsa–Wittig reagent DipTerAsPMe3 (DipTer= 2, 6-{2, 6-iPr2-C6H3}–C6H3) have been …

The study of new, unusual structures and reactivity patterns is of great interest for various
field of organic and organometallic chemistry. Metallacycles of electropositive transition …

Recently reported reactions of group 4 metallocene bis (trimethylsilyl) acetylene complexes
from the last two years are summarized. This could be considered as a never-ending story. A …