Best‐practice DFT protocols for basic molecular computational chemistry

M Bursch, JM Mewes, A Hansen… - Angewandte Chemie …, 2022 - Wiley Online Library
Nowadays, many chemical investigations are supported by routine calculations of molecular
structures, reaction energies, barrier heights, and spectroscopic properties. The lion's share …

DFT exchange: sharing perspectives on the workhorse of quantum chemistry and materials science

AM Teale, T Helgaker, A Savin, C Adamo… - Physical chemistry …, 2022 - pubs.rsc.org
In this paper, the history, present status, and future of density-functional theory (DFT) is
informally reviewed and discussed by 70 workers in the field, including molecular scientists …

A graph representation of molecular ensembles for polymer property prediction

M Aldeghi, CW Coley - Chemical Science, 2022 - pubs.rsc.org
Synthetic polymers are versatile and widely used materials. Similar to small organic
molecules, a large chemical space of such materials is hypothetically accessible …

Calculation of absolute molecular entropies and heat capacities made simple

P Pracht, S Grimme - Chemical science, 2021 - pubs.rsc.org
We propose a fully-automated composite scheme for the accurate and numerically stable
calculation of molecular entropies by efficiently combining density-functional theory (DFT) …

Nitrogen‐Rich Rigid Polybenzimidazole With Phosphoric Acid Shows Promising Electrochemical Activity and Stability for High‐Temperature Proton Exchange …

A Gao, W Wang, P Wang, H Wu, C Gong… - Advanced Functional …, 2023 - Wiley Online Library
Polybenzimidazoles (PBIs) are the most promising binders for the catalyst layer (CL) in high‐
temperature proton exchange membrane fuel cells (HT‐PEMFC). However, traditional …

Automated and efficient generation of general molecular aggregate structures

C Plett, S Grimme - Angewandte Chemie International Edition, 2023 - Wiley Online Library
Modeling intermolecular interactions of complex non‐covalent structures is important in
many areas of chemistry. To facilitate the generation of reasonable dimer, oligomer, and …

Metal-and halide-free, solid-state polymeric water vapor sorbents for efficient water-sorption-driven cooling and atmospheric water harvesting

M Wu, R Li, Y Shi, M Altunkaya, S Aleid, C Zhang… - Materials …, 2021 - pubs.rsc.org
Metal-and halide-free, solid-state water vapor sorbents are highly desirable for water-
sorption-based applications, because most of the solid sorbents suffer from low water …

Spin‐Crossover Grafted Monolayer of a Co (II) Terpyridine Derivative Functionalized with Carboxylic Acid Groups

V García‐López, N Giaconi, L Poggini… - Advanced Functional …, 2023 - Wiley Online Library
The synthesis and characterization of a new Co (II) spin‐crossover (SCO) complex based on
4′‐(4‐carboxyphenyl)− 2, 2′: 6′, 2 ″‐terpyridine ligand are reported. This complex can …

Searching the chemical space of bicyclic dienes for molecular solar thermal energy storage candidates

AE Hillers‐Bendtsen, JL Elholm… - Angewandte Chemie …, 2023 - Wiley Online Library
Photoswitches are molecular systems that are chemically transformed subsequent to
interaction with light and they find potential application in many new technologies. The …

Unlocking the computational design of metal–organic cages

A Tarzia, KE Jelfs - Chemical Communications, 2022 - pubs.rsc.org
Metal–organic cages are macrocyclic structures that can possess an intrinsic void that can
hold molecules for encapsulation, adsorption, sensing, and catalysis applications. As metal …