Coordinatively unsaturated metal sites (open metal sites) in metal–organic frameworks: design and applications
Ü Kökçam-Demir, A Goldman, L Esrafili… - Chemical Society …, 2020 - pubs.rsc.org
Metal–organic frameworks (MOFs) can contain open metal sites (OMS) or coordinatively
unsaturated sites (CUS) or open coordination sites (OCS) when vacant Lewis acid sites on …
unsaturated sites (CUS) or open coordination sites (OCS) when vacant Lewis acid sites on …
Generating catalytic sites in UiO-66 through defect engineering
UiO-66 is regarded as an epitome of metal–organic frameworks (MOFs) because of its
stability. Defect engineering has been used as a toolbox to alter the performance of MOFs …
stability. Defect engineering has been used as a toolbox to alter the performance of MOFs …
Boosting toluene oxidation by the regulation of Pd species on UiO-66: Synergistic effect of Pd species
X Zhang, F Bi, Z Zhao, Y Yang, Y Li, L Song, N Liu… - Journal of …, 2022 - Elsevier
Supported single-atoms and sub-nanometre clusters have exhibited superb catalytic
performance toward many reactions. However, inactivation of single-atom or cluster …
performance toward many reactions. However, inactivation of single-atom or cluster …
From fundamentals to applications: a toolbox for robust and multifunctional MOF materials
In recent years, metal–organic frameworks (MOFs) have been regarded as one of the most
important classes of materials. The combination of various metal clusters and ligands …
important classes of materials. The combination of various metal clusters and ligands …
A decade of UiO-66 research: a historic review of dynamic structure, synthesis mechanisms, and characterization techniques of an archetypal metal–organic …
UiO-66 is an archetypal metal–organic framework (MOF) with a very high surface area as
well as high thermal stability. It is found that the stability can be attributed to the metal oxide …
well as high thermal stability. It is found that the stability can be attributed to the metal oxide …
Imaging defects and their evolution in a metal–organic framework at sub-unit-cell resolution
Defect engineering of metal–organic frameworks (MOFs) offers promising opportunities for
tailoring their properties to specific functions and applications. However, determining the …
tailoring their properties to specific functions and applications. However, determining the …
Electronic structure modeling of metal–organic frameworks
Owing to their molecular building blocks, yet highly crystalline nature, metal–organic
frameworks (MOFs) sit at the interface between molecule and material. Their diverse …
frameworks (MOFs) sit at the interface between molecule and material. Their diverse …
Metal–organic and covalent organic frameworks as single-site catalysts
Heterogeneous single-site catalysts consist of isolated, well-defined, active sites that are
spatially separated in a given solid and, ideally, structurally identical. In this review, the …
spatially separated in a given solid and, ideally, structurally identical. In this review, the …
Surface-supported metal–organic framework thin films: fabrication methods, applications, and challenges
Surface-supported metal–organic framework thin films are receiving increasing attention as
a novel form of nanotechnology. New deposition techniques that enable the control of the …
a novel form of nanotechnology. New deposition techniques that enable the control of the …
Defect engineering: tuning the porosity and composition of the metal–organic framework UiO-66 via modulated synthesis
Presented in this paper is a deep investigation into the defect chemistry of UiO-66 when
synthesized in the presence of monocarboxylic acid modulators under the most commonly …
synthesized in the presence of monocarboxylic acid modulators under the most commonly …